On the existence of a mono-vinyl d-urobilin.

نویسندگان

  • M Chedekel
  • F A Bovey
  • A I Brewster
  • Z J Petryka
  • M Weimer
  • C J Watson
  • A Moscowitz
  • D A Lightner
چکیده

Chromic acid degradation of a d-urobilin, obtained after incubation of bilirubin in fecal bacterial cultures, gave methylvinylmaleimide and methylethylmaleimide. The d-urobilin, molecular weight 588, C(33)H(40)-N(4)O(6), clearly showed the presence of both vinyl and ethyl resonances in the nuclear magnetic resonance spectrum. These results point unambiguously to a urobilin structure with one vinyl and one ethyl beta-substituent.

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عنوان ژورنال:
  • Proceedings of the National Academy of Sciences of the United States of America

دوره 71 5  شماره 

صفحات  -

تاریخ انتشار 1974